陶瓷釉层结构色的多场耦合效应分析及光子色釉料的研究

项目名称： 陶瓷釉层结构色的多场耦合效应分析及光子色釉料的研究

项目编号： No.51472153

项目类型： 面上项目

立项/批准年度： 2015

项目学科： 一般工业技术

项目作者： 王芬

作者单位： 陕西科技大学

项目金额： 85万元

中文摘要： 结构色起源于自然光与物质微结构的相互作用，有着普通化学色难以企及的色彩美观与多功能性。本研究在分析陶瓷釉微观结构中分相结构呈色的基础上，通过蛋白石结构光子晶体结构生色的调制，反求研究分相瓷釉结构呈色机理与提高其结构呈色品质的方法；根据结构生色原理，集结构的干涉、衍射与散射等多种呈色功能于一体，制备不同核与壳@壳结构的微球材料－光子色料，结合其不同应用条件的分散介质、填充介质与基釉研究，进行陶瓷光子色釉料的基础研究。通过材料物性、结构有序度与尺寸效应、微量化学色剂及温度与光学外场效应等研究，结合SEM、TEM、DSC、激光拉曼、红外光谱、紫外可见光谱及色度等测试分析与计算，进行光子色釉料结构与带隙的可控制备与呈色机理研究，实现陶瓷色釉料的多色彩及高品质结构生色，为解决陶瓷色釉料及同类涂层材料制备中的高污染、高能耗与高成本难题，实现其绿色环保化生产及结构与功能的一体化开辟新途径。

中文关键词： 陶瓷釉；结构色；多场耦合；光子色釉料；呈色机制

英文摘要： Structural colors, originated from the interaction between light and the microstructures of materials, are more beautiful and versatile than the ordinary chemical colors. This research proposal aims to study the glaze structural color mechanism and obtain the methods of improving the quality of the structural color by the combination of preparation of photonic crystal opal structural color and analysis of phase separation structural color in the microstructure of ceramic glazes. Different core and core-shell@ shell structure microspheres materials, which has versatile color features (interference, diffraction, scattering, etc.), will be prepared according to the structural color mechanism. Based on the application conditions of different dispersion mediums, filling mediums and base glazes, photon pigments will be researched and developed. In order to achieve the band gap control and clarify the color mechanism of the photon pigments with high quality, the material properties, ordered periodic structure, quantum size effect, trace chemical reagent, and optical effects on temperature and light source about ceramic pigments, will be analyzed using the testing methods of SEM, TEM, DSC, LRS, FT-IR, UV-Vis spectra and the calculation of chromaticity. The researches will realize versatile colors and high-quality structural colors and develop a new way of green production and integration of structures and functions for ceramic pigments and glazes. High pollution, high energy-consumption and high cost of the production of ceramic pigments and glazes would be decreased.

英文关键词： ceramic glaze;structural color;multi-field coupling;photonic pigment and glaze;coloring mechanism