The volumes of Kostka polytopes appear naturally in questions of random matrix theory in the context of the randomized Schur-Horn problem, i.e., evaluating the probability density that a random Hermitian matrix with fixed spectrum has a given diagonal. We give a polynomial-time deterministic algorithm for approximating the volume of a ($\Omega(n^2)$ dimensional) Kostka polytope $\mathrm{GT}(\lambda, \mu)$ to within a multiplicative factor of $\exp(O(n\log n))$, when $\lambda$ is an integral partition with $n$ parts, with entries bounded above by a polynomial in $n$, and $\mu$ is an integer vector lying in the interior of the Schur-Horn polytope associated to $\lambda$. The algorithm thus gives asymptotically correct estimates of the log-volume of Kostka polytopes corresponding to such $(\lambda, \mu)$. Our approach is based on a partition function interpretation of the continuous analogue of Schur polynomials, and an associated maximum entropy principle.
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